Phase equilibrium in n-octane/water separation units: vapor pressures, vapor and liquid molar fractions

Liquid - Vapor Equilibrium/Distillation

Background The volatility of a compound is its ability to change into a vapor, or to evaporate at a particular temperature and pressure. The normal boiling point of a liquid usually allows comparison of its volatility to other materials, with lower boiling points indicating greater volatility, but this may be affected somewhat by the presence of other materials. Comparison of the concentration ...

Phase-equilibrium-dominated vapor-liquid-solid growth mechanism.

The vapor-liquid-solid (VLS) growth model has been widely used to direct the growth of one-dimensional (1D) nanomaterials, but the origin of the proposed process has not been experimentally confirmed. Here we report the experimental evidence of the origin of VLS growth. Al(69)Ni(31) alloyed particles are used as "catalysts" for growing AlN nanowires by nitridation reaction in N(2)-NH(3) at diff...

Gibbs ensemble simulation of liquid-vapor equilibrium in quantum neon

Harmony Search for Parameter Estimation in Vapor- Liquid Equilibrium Modeling

This study introduces the application of Harmony Search (HS) method for solving the parameter estimation problem in vapor-liquid equilibrium data modeling. The performance of this novel stochastic optimization strategy has been tested using several sets of binary vaporliquid equilibrium data with local composition models and the classical approach of least squares. Our results indicate that HS ...

Modelling and Simulation of Liquid-Vapor Phase Transition in Compressible Flows Based on Thermodynamical Equilibrium

In the present work we investigate the numerical simulation of liquid-vapor phase change in compressible flows. Each phase is modeled as a compressible fluid equipped with its own Equation of State (EOS). We suppose that inter-phase equilibrium processes in the medium operate at a short time-scale compared to the other physical phenomena such as convection or thermal diffusion. This assumption ...